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Properties of Mn-doped FINEMET

Identifieur interne : 004D26 ( Main/Repository ); précédent : 004D25; suivant : 004D27

Properties of Mn-doped FINEMET

Auteurs : RBID : Pascal:09-0249231

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English descriptors

Abstract

Structural, thermodynamical and magnetic properties of Fe73.5-xSi13.5B9Cu1Nb3Mnx amorphous alloys, with Mn content x = 1, 3-15, were studied by means of X-ray diffraction (XRD), differential scanning calorimetry (DSC), Mössbauer spectroscopy (MS) and energy-dispersive X-rays (EDX), as-quenched and after annealing. The alloys with x ≤ 7 suffer primary (above ∼550°C) and secondary (below ∼680°C) crystallisation, whereas the alloys with x ≥ 9 only at ∼580°C.Mn doping results in increase (for x ≤ 7) and then (forx > 9) in decrease of grain size. The hyperfine field of the amorphous precursor and remainder substantially decrease with increase of Mn content x, whereas the fields in crystallites remain nearly independent of x. A paramagnetic component appears at x ∼ 9 and grows with x.

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<name sortKey="Wasiak, M" uniqKey="Wasiak M">M. Wasiak</name>
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<term>Crystallization</term>
<term>Differential scanning calorimetry</term>
<term>Dispersive spectrometry</term>
<term>Grain size</term>
<term>Hyperfine magnetic field</term>
<term>Indium additions</term>
<term>Iron base alloys</term>
<term>Magnetic properties</term>
<term>Manganese additions</term>
<term>Manganese alloys</term>
<term>Moessbauer spectroscopy</term>
<term>Paramagnetic materials</term>
<term>Precursor</term>
<term>Thermodynamic properties</term>
<term>X-ray spectra</term>
<term>XRD</term>
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<div type="abstract" xml:lang="en">Structural, thermodynamical and magnetic properties of Fe
<sub>73.5-x</sub>
Si
<sub>13.5</sub>
B
<sub>9</sub>
Cu
<sub>1</sub>
Nb
<sub>3</sub>
Mn
<sub>x</sub>
amorphous alloys, with Mn content x = 1, 3-15, were studied by means of X-ray diffraction (XRD), differential scanning calorimetry (DSC), Mössbauer spectroscopy (MS) and energy-dispersive X-rays (EDX), as-quenched and after annealing. The alloys with x ≤ 7 suffer primary (above ∼550°C) and secondary (below ∼680°C) crystallisation, whereas the alloys with x ≥ 9 only at ∼580°C.Mn doping results in increase (for x ≤ 7) and then (forx > 9) in decrease of grain size. The hyperfine field of the amorphous precursor and remainder substantially decrease with increase of Mn content x, whereas the fields in crystallites remain nearly independent of x. A paramagnetic component appears at x ∼ 9 and grows with x.</div>
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B
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Cu
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amorphous alloys, with Mn content x = 1, 3-15, were studied by means of X-ray diffraction (XRD), differential scanning calorimetry (DSC), Mössbauer spectroscopy (MS) and energy-dispersive X-rays (EDX), as-quenched and after annealing. The alloys with x ≤ 7 suffer primary (above ∼550°C) and secondary (below ∼680°C) crystallisation, whereas the alloys with x ≥ 9 only at ∼580°C.Mn doping results in increase (for x ≤ 7) and then (forx > 9) in decrease of grain size. The hyperfine field of the amorphous precursor and remainder substantially decrease with increase of Mn content x, whereas the fields in crystallites remain nearly independent of x. A paramagnetic component appears at x ∼ 9 and grows with x.</s0>
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<s5>46</s5>
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